(i) Define the term functional group. Identify the functional group present in the following:

(ii) What happens when 5% alkaline KMnO 4 solution is added drop by drop to warm ethanol taken in a test-tube? State the role of alkaline KMnO 4 solution in this reaction.

 

Answer

(i) A functional group is a heteroatom or a group of atoms attached to the carbon chain which gives certain characteristic properties to a compound.

Structure of Formaldehyde - Teachoo.png

In the compound given above, there is an oxygen atom attached to the carbon atom through a double bond. 

So, the functional group is ketone.  

 

In the compound given above, there is an oxygen atom attached to the carbon atom through a double bond and an OH group attached through a single bond to the same carbon atom.

So, the functional group is carboxylic acid .

(ii) Alkaline KMnO 4 is an oxidising agent. On reaction with ethanol, KMnO 4 oxidises it to ethanoic acid and the reaction that takes place is as follows:

Reaction of Ethanol with Oxidizing Agent. - Teachoo.png

 

Go Ad-free

Transcript

Reaction of Ethanol with Oxidizing Agent Ethanol Oxygen (from the oxidizing agent) Oxidation Alkaline KMNO4 Acidified K2Cr2O7 Ethanoic acid

Maninder Singh's photo - Co-founder, Teachoo

Made by

Maninder Singh

CA Maninder Singh is a Chartered Accountant for the past 14 years and a teacher from the past 18 years. He teaches Science, Economics, Accounting and English at Teachoo