A dry pellet of a common base B when kept in open absorbs moisture and turns sticky. The compound is also a by-product of the chlor-alkali process.
(a) Identify B:
(i) Sodium chloride
(ii) Sodium hydroxide
(iii) Carbon dioxide
(iv) Sodium carbonate
Ans.
Given that
Common base Base B , when kept in open, absorbs moisture
Now,
- Chlor-Alkali process is a method for the industrial production of sodium hydroxide and chlorine by the electrolysis of sodium chloride solution.
-
Since B is a base,
it
cannot be
sodium chloride because it is a salt.
Therefore, B is sodium hydroxide (NaOH)
So, the correct option is (ii) Sodium hydroxide
(b) What type of reaction occurs when B is treated with an acidic oxide?
(i) Neutralisation
(ii) Double decomposition
(iii) Combination
(iv) Displacement
Ans.
Here,
- Neutralisation reaction : In this, acid and base react with each other to form salt and water.
- Double decomposition reaction: it is a reaction between two compounds in which each are interchanged to form two new compounds i.e. AB+CD→AC+BD
- Displacement Reaction: Reaction in which more reactive element takes the place of less reactive element.
-
Combination Reaction:
When two or more substances react to form a single product, it is known as combination reaction i.e. A+B→C+D
Since B is Sodium Hydroxide i.e a base , when we react it with an acidic oxide , neutralization reaction will take place.
So, the correct answer is (i)
(c) What is the raw material used in chloro-alkali?
(i) aqueous solution of sodium chloride
(ii) sodium chloride in dry form
(iii) sodium hydroxide
(iv) sodium carbonate
Ans.
- The raw material used in the chlor-alkali process is aqueous solution of sodium chloride , also known as brine .
-
We use aqueous NaCl and not dry NaCl because in
presence of water,
NaCl dissociates to produce Na
+
and Cl
-
ions which conduct electricity.
So, the correct answer is (i)
(d) When aqueous sodium carbonate (Na 2 CO 3 ) reacts with HCl (aq), it gives
(i) NaOH, H 2 and CO 2
(ii) NaCl, H 2 O and CO 2
(iii) NaHCO 3 , H 2 and CO 2
(iv) NaHCO 3 , H 2 O and CO 2
Ans.
Sodium carbonate is basic in nature. So, when it reacts with HCl (acid), a neutralisation reaction takes place and salt, water and CO 2 is produced.
The reaction is as follows:
Na 2 CO 3 (aq) + 2HCl(aq) → 2NaCl + H 2 O + CO 2
Therefore, the correct answer is
(ii) NaCl, H
2
O and CO
2